The generation and reactivity of oxygen
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Derek H.R. Barton; Joseph Cs. Jaszberenyi; Andrew I. Morrell
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Article
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1991
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Elsevier Science
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French
⚖ 227 KB
Oxygen centered radicals, formed by the photolysis of derivatives of N-hydroxy-2-thiopyridone, have been trapped by vinyl ethers. In the case of the benzoyloxy radical, smooth deoxygenation is effected by "'P compounds. Evidence for the formation of the dimethyltbutylsilyloxy and of the hydroxy rad