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Generation and the ambident character of 9-anthrylmethyl carbanions

✍ Scribed by T.A. Engler; H. Shechter

Book ID
104220064
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
282 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis

9_Methoxymethylanthracene, 9-trimethylsilylmethylanthracene and 9-thiomethoxymethylanthracene are converted by butyllithium reagents to a-methoxy-9-anthrylmethyl, atrimethylsilyl-9-anthrylmethyl and 9-anthrylmethyl carbanions, respectively, which react at their C-10 and C-11 positions with appropriate electrophiles.

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