Generation and reversible dimerization of the perfluoro-tert-hexyl radical
โ Scribed by B. L. Tumanskii; S. P. Solodovnikov; N. N. Bubnov; S. I. Pletnev; S. M. Igumnov; I. N. Rozhkov
- Book ID
- 112444725
- Publisher
- Springer
- Year
- 1988
- Tongue
- English
- Weight
- 57 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1573-9171
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๐ SIMILAR VOLUMES
The combination of high-performance liquid chromatography (HPLC) and ESR spectrometry was used to isolate the radical products obtained by photolysis of o-methylbenzaldehyde (l), o-methylacetophenone (2) and omethylbenzophenone (3) in the presence of a-phenyl-N-tert-butylnitrone and its derivatives
## Abstract The formation of a ternary complex between phenols, Co (II)โacetylacetonate and molecular oxygen has been established at ambient temperature and in nonโpolar solvents. After intramolecular electron transfer the transient magnified image radical enhances the homolytic scission of the ๏ฃฟO๏ฃฟ