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Generation and Reactivity of 1,2-Cyclohexadiene under Mild Reaction Conditions

✍ Scribed by Iago Quintana; Diego Peña; Dolores Pérez; Enrique Guitián

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 255 KB
Volume: 2009
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200900631

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✦ Synopsis

Abstract

An improved method to generate 1,2‐cyclohexadienes by fluoride‐induced β‐elimination of 6‐(trimethylsilyl)cyclohexenyl triflates is presented. This method allows the generation of these highly strained cyclic allenes in good yields and under mild reaction conditions, as demonstrated by trapping experiments based on cycloaddition reactions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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