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Generation and Reaction of Ammonium Ylides in Basic Two-Phase Systems

✍ Scribed by Anna Kowalkowska; Dorota Sucholbiak; Andrzej Jonczyk


Publisher
John Wiley and Sons
Year
2005
Weight
45 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Generation and Reaction of Ammonium Ylid
✍ Anna Kowalkowska; Dorota SuchoΕ‚biak; Andrzej JoΕ„czyk πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 154 KB

## Abstract Reaction of the quaternary ammonium salts **2a**–**i** with electrophilic alkenes **3**, active alkylating agents **7** or aromatic aldehydes **11**, carried out in basic two‐phase systems A–D, afforded cyclopropanes **4**, cyanoalkenes **8** or cyanooxiranes **12** respectively, via th