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Generation and decomposition of Group VIII metal (iron, cobalt, nickel) ion metallacycles in the gas phase

✍ Scribed by Jacobson, D. B.; Freiser, B. S.


Book ID
126927910
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
804 KB
Volume
3
Category
Article
ISSN
0276-7333

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## Ion -molecule reactions of (acac),M' ions (M = Fe, Co) with macrocyclic thiourea derivatives (L) were studied. The formation of acacML' and acacM(L -H)' were observed. AcacM(L -H)' ions arise from loss of the hydrogen atom of the NH group. The ion peak intensity ratios, Z = (acacML' J/[acacM(L