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Generalized method for determination of penultimate model reactivity ratios and analysis of data

✍ Scribed by Pramil C. Deb


Book ID
108249657
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
126 KB
Volume
48
Category
Article
ISSN
0032-3861

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πŸ“œ SIMILAR VOLUMES


A method for determining reactivity rati
✍ C.A. Barson; D.R. Fenn πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 143 KB

A novel kinetic treatment is proposed for the copolymerization of two monomers M~ and M 2 where the reactivities of all terminal groups are susceptible to penultimate group effects. By applying the conditions [Mt]>>[M2] and [MI]<<[M2], as is possible using radiolabelled monomers, values of r I and r

A Linearization Procedure for the Determ
✍ Franz Hinkelmann; Oskar Friedrich Olaj; Irene SchnΓΆll-Bitai πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 273 KB

## Abstract A newly developed method for the determination of the radical reactivity ratios is presented. Two main equations are used and the parameters can be calculated from the ordinate and the slope of the linearization plots. Both equations yield identical values when applied to synthetic data

Non-uniqueness in determination of termi
✍ Andrzej Kaim; PaweΕ‚ Oracz πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 593 KB

## Abstract The terminal and penultimate model reactivity ratios in the free‐radical copolymerization of styrene and methyl methacrylate in bulk at 40Β°C were calculated by means of the simplex and scanning methods. Calculations showed that for the terminal model __r__~1~ and __r__~2~ vary in compar