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General Synthesis and Structural Evolution of a Layered Family of Ln 8 (OH) 20 Cl 4 · n H 2 O (Ln = Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Y)

✍ Scribed by Geng, Fengxia; Matsushita, Yoshitaka; Ma, Renzhi; Xin, Hao; Tanaka, Masahiko; Izumi, Fujio; Iyi, Nobuo; Sasaki, Takayoshi


Book ID
120470354
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
768 KB
Volume
130
Category
Article
ISSN
0002-7863

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The novel title compounds are prepared in about 90% yield by hydrothermal reaction of Ln2O3 with stoichiometric amounts of H3BO3 (H2O, 220 °C, autoclave, 3 d). The structures are investigated by powder XRD and single crystal XRD for Nd2B6O10(OH)4•H2O. The isostructural compounds crystallize in the m