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General spin structures of organic radicals

✍ Scribed by Kizashi Yamaguchi

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
518 KB
Volume
30
Category
Article
ISSN
0009-2614

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✦ Synopsis

Changes of spin structures irthe course of chemical lcactiork have bedn investigated on the basis of the Heiscnberg mbdel, gsscmlig two different exchangoinlegrals.

It is found that an axial spin structure changes to another axial aqin ~stru,cturc passing through the torsional structrlre such as the trizngul+r spin arrangement in the cyclic threeclectron system.

The spin'$ructures of odd poljenic cyclic radiwls and the tetrahedral He radical are Also torsional spin arrangements.

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,I. Irltrodnction :'

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