General Route to Three-Dimensional Framework Uranyl Transition Metal Phosphates with Atypical Structural Motifs: The Case Examples of Cs 2 {(UO 2 ) 4 [Co(H 2 O) 2 ] 2 (HPO 4 )(PO 4 ) 4 } and Cs 3+ x [(UO 2 ) 3 CuH 4- x (PO 4 ) 5 ]·H 2 O
✍ Scribed by Shvareva, Tatiana Y.; Albrecht-Schmitt, Thomas E.
- Book ID
- 127026369
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 145 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0020-1669
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The hydrothermal syntheses and structures of two new open-framework iron phosphates, I, [C 6 N 2 H 14 ][Fe III 2 F 2 (HPO 4 ) 2 (H 2 PO 4 ) 2 ].2H 2 O, II, and [C 6 N 2 H 14 ] 2 [Fe III 3 (OH)F 3 (PO 4 ) (HPO 4 ) 2 ] 2 . H 2 O, are presented. The structures of both I and II consist of FeO 4 F 2 octa
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