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General and Regioselective Synthesis of Pyrroles via Ruthenium-Catalyzed Multicomponent Reactions

โœ Scribed by Zhang, Min; Fang, Xianjie; Neumann, Helfried; Beller, Matthias

Book ID
120582886
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
776 KB
Volume
135
Category
Article
ISSN
0002-7863

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## Abstract Enantioselective syntheses of several paraconic acids have been achieved using catalyzed asymmetric hydrogenation of ฮฒโ€keto esters with SYNPHOS^ยฎ^ as a ligand. This strategy allowed the short synthesis of biologically active (โˆ’)โ€methylenolactocin **1**, (โˆ’)โ€protolichesterinic acid **2**