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Geminate ion-electron recombination kinetics in non-polar liquids by time-resolved fluorescence

✍ Scribed by Ann M. Brearley; Ramesh C. Patel; Daniel B. McDonald

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
685 KB
Volume
140
Category
Article
ISSN
0009-2614

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✦ Synopsis

The dynamics of geminate ion-electron recombination following laser photoionization of N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD) in non-polar solution were observed by time resolving the resulting delayed fluorescence. Geminate recombination was observed for TMPD excited by intense (3 pJ) picosecond pulses of 305 nm light in low electron mobility solvents. Preliminary comparisons were made to theoretical models.

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