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Geminate and volume electron—cation recombination in a polyatomic buffer gas

✍ Scribed by G.A. Abakumov; V.B. Kolovsky; B.I. Polyakov; A.P. Simonov

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
460 KB
Volume
182
Category
Article
ISSN
0009-2614

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✦ Synopsis

The yields of electrons (or cations) generated by the stepwisc two-photon laser gas-phase photoionization of 2,S-diphenylfuran and 1 ,bbeniranthracene and the rate constants of volume electron-cation recombination in a polyatomic buffer gas (pentane) have been measured. Geminate recombination has been found to take place and the cage escape probability has been determined. For pressures of pentane greater than 200 Torr, volume recombination has been shown to be of the Langevm type.

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