Geminal Bis(hypersilyl) Compounds: The Synthesis and Structure of Bis[tris(trimethylsilyl)silyl]methane
β Scribed by Gross, Thoralf; Oehme, Hartmut; Kempe, Rhett
- Book ID
- 126024152
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 55 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
Methane, methoxybis[tris(trimethylsilyl)silyl-/ Tris(trimethylsily1)silyllithium / Dichloromethyl methyl ether / ## Poly silanes Methoxy-bis[tris(trimethylsilyl)silyl]methane (4), the first compound bearing two hypersilyl groups at a carbon atom, was synthesized by the reaction of tris(trimethyls
trimethylsilyl)silanes / (Chloromethylene)ammonium chlorides Tris(trimethylsilyl)silyllithium (1) reacts with dialkyl-5c: 1.99 and 1.97 A Λ) and an extreme widening of the SiΟͺCΟͺSi angles at the central sp 3 -carbon atoms (5a: 132.6Β°; (chloromethylene)ammonium chlorides (molar ratio 2:1) to give the