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Geminal Bis(hypersilyl) Compounds: The Synthesis and Structure of Bis[tris(trimethylsilyl)silyl]methane

✍ Scribed by Gross, Thoralf; Oehme, Hartmut; Kempe, Rhett


Book ID
126024152
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
55 KB
Volume
18
Category
Article
ISSN
0276-7333

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trimethylsilyl)silanes / (Chloromethylene)ammonium chlorides Tris(trimethylsilyl)silyllithium (1) reacts with dialkyl-5c: 1.99 and 1.97 A ˚) and an extreme widening of the SiΟͺCΟͺSi angles at the central sp 3 -carbon atoms (5a: 132.6Β°; (chloromethylene)ammonium chlorides (molar ratio 2:1) to give the