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[GdNi6] and [LaNi6]: High-Field EPR Spectroscopy and Magnetic Studies of Exchange-Coupled Octahedral Clusters

✍ Scribed by Yasuhiko Yukawa; Guillem Aromí; Satoshi Igarashi; Joan Ribas; S. A. Zvyagin; J. Krzystek

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 135 KB
Volume: 44
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200462401

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## Abstract Two new azido‐bridged polyoxometalate compounds were synthesized in acetonitrile/methanol media and their molecular structures have been determined by X‐ray crystallography. The [{(γ‐SiW~10~O~36~)Mn~2~(OH)~2~(N~3~)~0.5~(H~2~O)~0.5~}~2~(μ‐1,3‐N~3~)]^10−^ (1 a) tetranuclear Mn^III^ comple