The first carbon-13 shift thermometer for the temperature range of 100 -300 K is based on the very rapid equilibration of a pair of semibullvalene valence tautomers. The temperature dependence of the equilibrium constant is reflected in strongly temperature-dependent shift differences ⌬␦ between ave
✦ LIBER ✦
Gas thermometer for precision measurement of thermodynamic temperatures below 300°K
✍ Scribed by S. P. Polunin; D. N. Astrov; L. B. Belyanskii; Yu. A. Dedikov; A. A. Zakharov
- Publisher
- Springer US
- Year
- 1987
- Tongue
- English
- Weight
- 514 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0543-1972
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An analysis is given of the errors which may be involved in D c' H a a s and W i e r s m a's method for obtaining the thermodynamic scale of temperature below 1°K and it is shown that an estimate of these errors may be obtained from a fairly rough determination of adiabatic M, H curves. As an exampl