✦ LIBER ✦

Gas sorption and diffusion processes in polymer matrices at high pressures

✍ Scribed by M. A. Krykin; V. I. Bondar; Yu. M. Kukharsky; A. V. Tarasov

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 215 KB
Volume: 35
Category: Article
ISSN: 0887-6266
DOI: 10.1002/(sici)1099-0488(19970715)35:9<1339::aid-polb4>3.0.co;2-h

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✦ Synopsis

A theoretical approach has been developed to describe the processes of gases diffusion and sorption in rubbery and glassy polymers. Various models (Flory-Huggins, dual-mode sorption, gas-polymer-matrix) used for interpreting the sorption-diffusion experiments are discussed within this approach framework. Experimental data on carbon dioxide sorption in glassy and rubbery polymers have been considered using the proposed approach. The comparison of the experimental and theoretical data has permitted to make the conclusion on the developed concepts adequacy.

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