Gas, solution, and solid state coordination environments for the nickel(II) complexes of a series of aminopyridine ligands of varying coordination number
β Scribed by JudithAnn R Hartman; Richard W Vachet; John H Callahan
- Book ID
- 108331847
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 114 KB
- Volume
- 297
- Category
- Article
- ISSN
- 0020-1693
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π SIMILAR VOLUMES
The complexation behavior of three chiral, tripodal N,O,Sligands with nickel(I1) salts was examined. It was found that the coordination mode of the ligands (bidentate N,O and N,S; tridentate N,O,S) and of the central nickel ion (square-planar vs. pseudo-octahedral) is not simply an intrinsic propert
The X-ray molecular structure and, magnetic, and spectroscopic properties, as well as the analysis of the structural behavior in solution of a novel nickel (II) complex [Ni 2 (HBPClNOL) 2 (OAc)](ClO 4 ) 1 are reported. Complex 1 was prepared by the reaction between the ligand H 2 BPClNOL (N-(2-hydro