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Gas phase substitution reactions by radical cations. Part 3. Methylene transfer of the CC ring-opened oxirane radical cation to pyrazole and imidazole

✍ Scribed by C.G. de Koster; J.J. van Houte; J. van Thuijl


Book ID
107920626
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
796 KB
Volume
134
Category
Article
ISSN
0168-1176

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Methylene radical cation transfer from i
✍ Margot W. van Amsterdam; Herman W. Zappey; Steen Ingemann; Nico M. M. Nibbering 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 626 KB

The a-distonic sulphur-containing ion 'CH,&CH,), has been generated by transfer of CH: ' from ionized oxirane to dimethyl thioether and distinguished from the molecular ion of ethyl methyl thioether by collision induced dissociation (CID) experiments. In particular, the a-distonic ion expels CH, to