Results of mass analyzed ion kinetic energy (MIKE) spectra and kinetic energy release (KER) measurements of diastereomeric octahedral cobalt complexes indicate that these diastereomers can be distinguished in the gas phase. Four alkyl tartrate esters were complexed to cobalt trisacetylacetonate (Co(
Gas-phase reactivity of diastereomeric acetate ion/tributylborate complexes
✍ Scribed by Antonello Filippi; Maurizio Speranza
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 240 KB
- Volume
- 199
- Category
- Article
- ISSN
- 1387-3806
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functional theory calculations were also carried out using B3-LYP [26] and M06-2X [27] along with the aug-cc-pVDZ and 6-31G(2df,p) basis sets, and subsequent single-point energies were computed at the CCSD(T), BD(T), [28] and CAS-AQCC [29] levels of theory with the aug-cc-pVQZ basis set. All of the
## Abstract **Aerial pingpong**: The lithium acetate enolate anion, the prototypical lithium salt of an α‐deprotonated carboxylate, was prepared in the gas phase by electrospray ionization (ESI) and collision‐induced ionization (CID). Its structure, reactivity, and energetics are presented along wi