Gas-Phase Reactions of U + and U 2+ with O 2 and H 2 O in a Quadrupole Ion Trap
โ Scribed by Jackson, Glen P.; King, Fred L.; Goeringer, Douglas E.; Duckworth, Douglas C.
- Book ID
- 127356327
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 92 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
The gas-phase ion-molecule reactions of the phosphonium ion formed by electron impact with OP(OCH 3 ) 2 ' neutral trimethyl phosphite were studied with the use of a quadrupole ion trap (QIT) mass spectrometer. Observed reactions include competing methoxy transfers between and the neutral species to
## Abstract Kinetic investigations on the reaction between U(IV) and H~2~O~2~ have been carried out at different acidities in chloride medium at an ionic strength of 2__M__. The observed bimolecular rate constant has been found to be dependant on [H^+^]^โ1.3^. The activation energy of the overall r