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Gas-phase reactions of O(3P) atoms with methanethiol, ethanethiol, methyl sulfide, and dimethyl disulfide. 1. Rate constants and Arrhenius parameters

✍ Scribed by Nip, W. S.; Singleton, D. L.; Cvetanovic, R. J.

Book ID: 126165588
Publisher: American Chemical Society
Year: 1981
Tongue: English
Weight: 598 KB
Volume: 103
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00402a045

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## Abstract Absolute rate coefficients for the gas‐phase reactions of CF~2~CFCl and (__E__/__Z__)‐CFClCFCl with O(^3^P) atoms have been measured at 298 K using a discharge flow tube coupled to a chemiluminescence detection system. The observed rate constant values are (4.5 ± 0.4) × 10^−13^ and (1