## OMS Letters Dear Sir, ## Gas-phase Reactions of the Sulphur Distonic Ion (CH,),SCH,' with Alkenes Distonic ions are well recognized as key intermediates in the unimolecular reactions of radical cations in the gas phase'-, and the bimolecular chemistry of these species has been described in a
Gas phase reactions of chloride ion with aryl-substituted nitrocyclohexenes
✍ Scribed by K. G. Das; A. Mahender Reddy; M. Mallaiah; K. P. Madhusudanan
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 208 KB
- Volume
- 20
- Category
- Article
- ISSN
- 1076-5174
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Gas-phase nucleophilic substitution reactions of Y-benzyl chlorides with X-phenoxide and Xthiophenoxide nucleophiles were investigated theoretically using the PM3 semi-empirical MO method. The Leffler-Grunwald rate-equilibrium and Brønsted correlations predict that the degree of bond formation in th
## Abstract Fourier‐transform ion cyclotron resonance mass spectrometry has been used to examine gas‐phase reactions of four different nitroxide free radicals with eight positively charged pyridyl and phenyl radicals (some containing a Cl, F, or CF~3~ substituent). All the radicals reacted rapidly