## Abstract The reaction of singlet oxygen with 2‐phenylnorbornene (**1**) in aprotic solvents gives 3‐formylcyclopentyl phenyl ketone (**2**) (10%) and uncharacterized polymer (90%). When methanol is used as solvent, __endo__‐2‐phenyl‐__exo__‐2‐methoxy‐__exo__‐3‐hydroperoxynorbornane (**4**) and _
✦ LIBER ✦
Gas-phase reactions of carbanions with triplet and singlet molecular oxygen
✍ Scribed by Schmitt, Robert J.; Bierbaum, Veronica M.; DePuy, C. H.
- Book ID
- 126296894
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 391 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The reactions of singlet molecular oxygen (O~2~^1^Δ~g~) with a series of organic compounds have been studied in the gas phase at 298°K. The concentration of singlet molecular oxygen was determined by titration with 2,5‐dimethylfuran. The titration technique was checked using a photoioni