✦ LIBER ✦
Gas-phase reactions of benzene and derivatives triggered by hydrazine/ozone; hydroxylation vs. degradation
✍ Scribed by Veronica M. Sol; Peter Mulder; Robert Louw
- Book ID
- 104589248
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 541 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0165-0513
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The reactions of benzene derivatives C~6~H~5~X (X = H, Cl, CH~3~ and CF~3~) with hydrazine and ozone in the dark (a source of OH radicals) have been studied in a flow reactor at ambient temperature.
(Substituted) phenols were formed, but these were relatively unimportant compared to N‐heterocyclic compounds (condensation products of cis‐butenedial and analogues with hydrazine) and other (degradation) products.
Benzene and (trifluoromethyl)benzene follow a similar path as toluene, also with oxidative ring opening as major reactions.