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Gas-Phase Reactions of Atomic Lanthanide Cations with D2O: Room-Temperature Kinetics and Periodicity in Reactivity

✍ Scribed by Ping Cheng; Gregory K. Koyanagi; Diethard K. Bohme


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
283 KB
Volume
7
Category
Article
ISSN
1439-4235

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Gas-phase hydrogen-deuterium (H/D) exchange reactions involving four isomeric cyclopropane derivatives were investigated under chemical ionization (CI) conditions, using D(2)O and CD(3)OD as reagent gases. There are abundant ions at [M + 1](+), [M + 2](+) and [M + 3](+) in the D(2)O and CD(3)OD posi