The effects of the introduction of chlorine substituents onto phenol on the rates of, and products from, their slow combustion at 500-550 Β°C are described. Competitive experiments showed that phenol, ortho-chlorophenol, 2,4,6-trichlorophenol and pentachlorophenol differ little in their overall rates
Gas-phase radiation-chemical formation of dioxins from chlorinated phenols
β Scribed by G. Ya. Gerasimov
- Book ID
- 110164548
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2007
- Tongue
- English
- Weight
- 166 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0018-1439
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The title reactions have been studied to scrutinize rate data this basis, the displacements of Cl and Br from the benzene ring by phenoxy radicals must have activation energies recently inferred for the two reverse steps -reaction of phenoxy radicals with chlorobenzene and bromobenzene -above 20 kca
The homogeneous, gas-phase formation of polychlorinated dibenzo-p-dioxins (PCDD) and polybrominated dibenzo-p-dioxins (PBDD) has been observed from the high-temperature thermal decomposition of 2,4,6trichlorophenol (2,4,6-TCP) and 2,4,6-tribromophenol (2,4,6-TBP), respectively. Experiments were cond