The gas-phase pyrolysis of 3-chloroquadricyclane [1] was investigated over the temperature range 513-550 K at one atm in helium. The initial pyrolysis step is the isomerization of 3-chloroquadricyclane to 7-chloronorbornadiene (E ϭ 39.63 Ϯ 1.40 kcal/mole, a 7-chloronorbornadiene rearranges (623-660
Gas-phase pyrolysis of coumaran and 2,3-dimethylcoumaran
✍ Scribed by Marcel van Meurs; Isabel W. C. E. Arends; Robert Louw; Peter Mulder
- Book ID
- 104589368
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 122 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0165-0513
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