𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Gas-Phase Pyrolyses of 2-Nitropropane and 2-Nitropropanol: Shock-Tube Kinetics

✍ Scribed by Zhang, Yi-Xue; Bauer, S. H.

Book ID
126278235
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
149 KB
Volume
104
Category
Article
ISSN
1089-5639

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics of the pyrolyses of endo- and e
Kinetics of the pyrolyses of endo- and exo-5-methylbicyclo (2.2.2) oct-2-ene in the gas phase
✍ G. Huybrechts; G. Ngoy 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 389 KB 👁 1 views

## Abstract The pyrolyses of endo‐ and exo‐5‐methylbicyclo (2.2.2) oct‐2‐ene (endo‐ and exo‐MBO) have been studied between 608 and 679°K at pressures between 7 and 37 torr. These reactions correspond to parallel first‐order eliminations of propene and ethylene: equation image The rate constants (

Kinetics and Mechanism of Prephase State
Kinetics and Mechanism of Prephase State Accumulation and Phase Transition in Crystals of 2-Bromo-2-Nitropropane-1,3-Diol
✍ N.I. Golovina; A.V. Raevskii; B.S. Fedorov; I.G. Gusakovskaya; R.F. Trofimova; L 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 354 KB

The structure of two phases of 2-bromo-2-nitropropane-1,3diol (1,2) synthesized by two different methods has been investigated. Calorimetric measurements of temperature behavior of crystals I and II have been conducted, with the crystals manifesting phase transition in a wide temperature range, 193-

The gas-phase elimination kinetics of et
The gas-phase elimination kinetics of ethyl 2-furoate and ethyl 2-thiophenecarboxylate
✍ Liliany Espitia; Ruby Meneses; Rosa M. Dominguez; Maria Tosta; Armando Herize; J 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 158 KB

## Abstract The gas‐phase elimination kinetics of ethyl 2‐furoate and 2‐ethyl 2‐thiophenecarboxylate was carried out in a static reaction system over the temperature range of 623.15–683.15 K (350–410°C) and pressure range of 30–113 Torr. The reactions proved to be homogeneous, unimolecular, and obe

Kinetics of gas-phase decomposition of o
Kinetics of gas-phase decomposition of oxetan and oxetan-2,2-d2
✍ L. Zalotai; Zs. Hunyadi-zoltán; T. Bérces; F. Márta 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 622 KB

## Abstract The pressure dependence of the first‐order rate coefficient of oxetan and oxetan‐2,2‐__d__~2~ decomposition has been studied in the pressure range from about 7 kPa down to 0.01 kPa at various temperatures between 673 and 758 K. Experimental data were analyzed using RRKM theory. Interpre

The gas-phase elimination kinetics of 2-
The gas-phase elimination kinetics of 2-hydroxy-2-methylbutyric acid and 2-ethyl-2-hydroxybutyric acid
✍ Gabriel Chuchani; Ignacio Martin; Alexandra Rotinov 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB 👁 1 views

The elimination kinetics of the title compounds have been examined over the temperature range of 270-320°C and pressure range of 19-117 torr. The reactions, carried out in seasoned vessels, with the free-radical suppressor toluene always present, are homogeneous, unimolecular, and follow a first-ord