Gas phase photolysis of acetone in the far ultra-violet
β Scribed by Lawrence Ju-Te Lin; P. Ausloos
- Publisher
- Elsevier Science
- Year
- 1972
- Weight
- 785 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0047-2670
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Photodecomposition of dimethylnitrosamine in the gas phase (-1 Torr) has been investigated following irradiation into the S, ( n n \* ) t S , (363.5 nm) and S, ( m \* ) t S , (248.1 nm) transitions at room temperature. With a quantum yield of unity, excitation into the S, state yields the fragments
## Abstract Mass spectrometryβbased methods have been employed in order to study the reactions of nonβ (__h__~6~/__h__~6~), half (__d__~6~/__h__~6~), and fully (__d__~6~/__d__~6~) deuterium labeled protonated dimers of acetone in the gas phase. Neither kinetic nor thermodynamic isotope effects were