Hexafluoro acetone CF 3 COCF 3 has been shown to react rapidly with the CH 2 OO, CH 3 CHOO, and (CH 3 ) 2 COO intermediates that are formed in the ozonolysis of C 2 H 4 , trans-2-C 4 H 8 , and 2,3-dimethyl-2-butene, respectively, and to form products tentatively assigned to the corresponding seconda
Gas-Phase Ozonolysis of Selected Olefins: The Yield of Stabilized Criegee Intermediate and the Reactivity toward SO 2
✍ Scribed by Berndt, Torsten; Jokinen, Tuija; Mauldin, Roy L.; Petäjä, Tuukka; Herrmann, Hartmut; Junninen, Heikki; Paasonen, Pauli; Worsnop, Douglas R.; Sipilä, Mikko
- Book ID
- 121324221
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 664 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1948-7185
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Ozonolysis of cis-and trans-2-butene isomers were carried out in a 570 l spherical glass vessel in 730 torr synthetic air at 295 Ϯ 3 K. The initial concentrations were 5 to 10 ppmv for the isomers and 2 to 5 ppmv for ozone. Quantitative yields were determined by FTIR spectroscopy for CH 3 CHO, HCHO,
## Abstract The gas‐phase reactions of O~3~ with 1‐octene, __trans__‐7‐tetradecene, 1,2‐dimethyl‐1‐cyclohexene, and α‐pinene have been studied in the presence of an OH radical scavenger, primarily using in situ atmospheric pressure ionization tandem mass spectrometry (API‐MS), to investigate the pr