The reactions of metastable decomposing methyl acetoacetate (a mixture of keto and enol tautomers) are reported and discussed. The unimolecular fragmentations of the tautomers are different. The metastable decomposing radical cation of the keto form displays four specific ions: [ M -CO] +', IM -CHzO
β¦ LIBER β¦
Gas-phase organic reactions of the atomic oxygen radical cation
β Scribed by Nichols, Charles M.; Yang, Zhibo; Bierbaum, Veronica M.
- Book ID
- 121306210
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 865 KB
- Volume
- 353
- Category
- Article
- ISSN
- 1387-3806
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