Gas-Phase negative ion hetero retro-diels-alder reaction
✍ Scribed by David J. Burinsky; Richard Dunphy; J. Douglas Alvessantana; Mary Lou Cotter
- Book ID
- 102559341
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 170 KB
- Volume
- 26
- Category
- Article
- ISSN
- 1076-5174
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📜 SIMILAR VOLUMES
A resin-bound furan has been efficiently synthesized from Merrifield resin. This new polymer reacts with an acetylenic dienophile to afford a thermally stable Diels-Alder adduct. Transformation of the adduct by Michael reaction with thiophenol has allowed an easy retro Diels-Alder reaction. This 'sa
## Abstract For Abstract see ChemInform Abstract in Full Text.
Bornylene (3,7, hept-2-ene) undergoes a retro-Diels-Alder reaction at elevated temperatures in the gas phase to yield ethylene and 1,5,5-trimethylcyclopentadiene. The product 1,5,5-trimethylcyclopentadiene is unstable and a methyl shift occurs, giving rise to an equilibrium mixture of four C8 hydro