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Gas-Phase Kinetics of Hydroxyl Radical Reactions with C 3 H 6 and C 4 H 8 : Product Branching Ratios and OH Addition Site-Specificity

✍ Scribed by Loison, Jean-Christophe; Daranlot, Julien; Bergeat, Astrid; Caralp, Françoise; Mereau, Raphaël; Hickson, Kevin M.

Book ID
127304756
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
585 KB
Volume
114
Category
Article
ISSN
1089-5639

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A shock-tube study of the kinetics of re
A shock-tube study of the kinetics of reaction of hydroxyl radicals with H2, CO, CH4, CF3H, C2H4, and C2H6
✍ J. N. Bradley; W. D. Capey; R. W. Fair; D. K. Pritchard 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 585 KB

Concentration-time profiles have been measured for hydroxyl radicals generated by the shock-tube decomposition of hydrogen peroxide in the presence of a variety of additives. At temperatures close to 1300"K, the rate constants for the reaction OH + R H + R + HzO arr found to be in the ratio 0.18:0.