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Gas-phase infrared spectroscopy of cyclopropane-HF and cyclopropane-HCN

โœ Scribed by D.C. Dayton; R.E. Miller

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
522 KB
Volume
153
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The optothermal detection method has been used to obtain gas-phase infrared spectra of the cyclopropane-HF and cyclopropane-HCN binary complexes, both of which show substantial homogeneous broadening. Shifted somewhat from the spectrum of the HF binary complex is an additional band which is tentatively assigned to a larger complex which contains both cyclopropane and HF.

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## Abstract At temperatures of 356โ€425ยฐC and pressures of 15โ€“60 Torr, cyclopropylamine reacts to give an equimolar mixture of ammonia and Nโ€propylidenecyclopropylamine as the initial product. The reaction is first order, homogeneous, and unaffected by the presence of radical inhibitors, and thus pr