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Gas phase hydrogen-deuterium exchange reactions in carbanions: exchange of vinyl and aryl protons by water-d2

โœ Scribed by Squires, Robert R.; DePuy, C. H.; Bierbaum, Veronica M.


Book ID
127193147
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
391 KB
Volume
103
Category
Article
ISSN
0002-7863

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Gas-phase noncovalently bound complexes are probed by hydrogen/deuterium exchange. The complexes, composed of a protonated amino acid and a monosaccharide, are investigated to observe the effects of complexation on the rates of exchange. Rate constants are determined and compared for complexed and u