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Gas-phase halo alkylation of C60-fullerene by ion-molecule reaction under chemical ionization

✍ Scribed by R. Srinivas; M. Vairamani; C.K. Mathews

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
293 KB
Volume
4
Category
Article
ISSN
1044-0305

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✦ Synopsis

Chemical ionization (CI) mass spectra of C60-fullerene were studied using 1,2-dibromoethane and 1,2-dichloroethane as CI reagents. The ion-molecule reaction between C60 and C2H4X(+) (X=Br and Cl) leads to the formation of (C60+C2H4X)(+) adducts. The collision-induced dissociation of the adducts reveal gas phase halo alkylation of C60-fullerence involving the C-C bond formation.

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