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Gas-Phase Generation and Electronic Structure Investigation of Oxidovanadium Triisocyanate, OV(NCO)3

✍ Scribed by Maofa Ge; Weigang Wang; Shi Yin; Carlos O. Della Védova

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
461 KB
Volume
2008
Category
Article
ISSN
1434-1948

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✦ Synopsis

Abstract

Oxidovanadium triisocyanate was generated from the heterogeneous reaction of gaseous vanadium trichloride oxide with silver cyanate and studied for the first time in the gas phase. The reaction processes were studied in situ by ultraviolet photoionization mass spectrometry combined with quantum chemical calculations and ultraviolet photoelectron spectrometry. The geometric and electronic structures were characterized and discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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