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Gas-Phase Generation and Characterization of Hydrogen CyanideN-Methylide

✍ Scribed by Goldberg, Norman ;Iraqi, Muhammad ;Schwarz, Helmut


Publisher
Wiley (John Wiley & Sons)
Year
1993
Tongue
English
Weight
240 KB
Volume
126
Category
Article
ISSN
0009-2940

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## Abstract A new isomer of diazomethane 1, the nitrile imine, HCNNH (2) is reported to be a stable molecule in the gas phase. Upon neutralizing the α‐distonic HCNNH^+^ cation in a beam experiment, this long‐time predicted ylide can be generated. The experiments are supported by theoretical calcula