The kinetics of the gas-phase elimination of several chloroesters were determined in a static svstem over the temperature range of 410-490OC and the pressure range of 47-236 torr. T h e reactions in seasoned vessels, and in the presence of a free-radical inhibitor, are homogeneous, unimolecular, and
โฆ LIBER โฆ
Gas-phase elimination kinetics of (dimethylamino)alkyl acetates. The ion-pair mechanism through neighboring group participation
โ Scribed by Chuchani, Gabriel; Rotinov, Alexandra; Dominguez, Rosa M.; Gonzalez, Neil
- Book ID
- 121290284
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 471 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3263
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The gas phase elimination of methyl 4-chlorobutyrate and methyl 5-chlorovalerate has been reexamined, in a static system and seasoned vessel, over the temperature range of 419.6-472.1"C and pressure range of 45-108 tom. The reactions, under maximum inhibition with propene, are homogeneous, unimolecu