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Gas-Phase Deprotonation of Uracil−Cu 2+ and Thiouracil−Cu 2+ Complexes

✍ Scribed by Lamsabhi, Al Mokhtar; Alcamí, Manuel; Mó, Otilia; Yáñez, Manuel; Tortajada, Jeanine

Book ID
119955985
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
595 KB
Volume
110
Category
Article
ISSN
1089-5639

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Deprotonation studies of Cu+–guanine and
Deprotonation studies of Cu+–guanine and Cu2+–guanine complexes by theoretical investigation
✍ Dianxiang Xing; Xuejie Tan; Xuebing Jiang; Bing Wang 📂 Article 📅 2011 🏛 Elsevier 🌐 English ⚖ 718 KB

The acidities of multiple sites in Cu + -guanine and Cu 2+ -guanine complexes have been investigated theoretically. To compare, the acidities of guanine (G) and guanine radical cation (G Å+ ) have also been included. The results clearly indicate that the acidities of CAH or NAH groups in Cu +/2+ -gu