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Gas-phase cyclisation reactions of 1-(2-arylthiophenyl)alkaniminyl and 2-(aryliminomethyl)thiophenoxyl radicals

✍ Scribed by Creed, Tim; Leardini, Rino; McNab, Hamish; Nanni, Daniele; Nicolson, Iain S.; Reed, David

Book ID
121308418
Publisher
Royal Society of Chemistry
Year
2001
Weight
187 KB
Volume
9
Category
Article
ISSN
1472-7781

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The rate of decomposition of 2-pentoxy radical to acetaldehyde and n-propyl radical has been studied in the presence of NO in competition with nitrite formation at and above 200 kPa pressure over the temperature range of 363-413 K. The rate coefficient for the decomposition is given as log(k,,/s-')