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Gas-Phase and Solution Basicities of Some Alkyl 2,6-Dialkylphenyl Ketones: a Comparative Analysis

✍ Scribed by Carlo Dell'Erba; Michelangelo Gruttadauria; Angelo Mugnoli; Renato Noto; Marino Novi; Giorgio Occhiucci; Giovanni Petrillo; Domenico Spinelli

Book ID: 104202751
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 165 KB
Volume: 56
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(00)00370-7

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Abstmct: The behaviour towards gas-phase protonation of a series of 2,6-dimethyl-4-X-acetophenones DMl exhibits strong similarities with that of the corresponding 4-X-acetophenones 1. A comparison with previous hasicity data in solution and AM1 semiempirical calculations suggest that the X-dependent

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