Gas-Phase Acid-Induced SN2′ versus SN2 Mechanism in Allylic Alcohols
✍ Scribed by Prof. Gabriele Renzi; Dr. Antonietta Lombardozzi; Dr. Emanuela Dezi; Prof. Adriano Pizzabiocca; Prof. Maurizio Speranza
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 892 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
The gas-phase acidities ∆G acid (298 K) of the sulfanes H 2 S n may be compared to those of other strong Brønsted acids like gaseous HNO 2 (1396), HCl (1371), and HBr (1332). The (n = 1-4) have been calculated by ab initio molecular orbital theory using the G2 and G2(MP2) methods, which were monoani
The competition between substitution (sN2), elimination (E2) and additiorrelimination (AE) reactions in the gas phase has been studied by using OH-and NH,as nucleophiles reacting with esters of acetylenedicarboxylic acid of general formula RO(O)CCZCC(O)OR'. By selectively varying R and R' it was pos