Cover......Page 1
Half Title......Page 2
Series Page......Page 3
Title Page......Page 8
Copyright Page......Page 9
Dedication......Page 10
Preface......Page 12
Table of Contents......Page 14
Chapter 1 Introduction to Gas-Liquid-Solid Chromatography......Page 18
References......Page 32
Chapter 2 Absolute Retention of Analyzed Compounds......Page 35
2.1 A model of the sorbent in gas-liquid-solid chromatography......Page 39
2.2 Variation of the sorbent surface in gas-liquid-solid chromatography as a function of the content of the stationary liquid phase on the solid support......Page 43
2.3 Principles of equilibrium theory of retention in gas-liquid-solid chromatography......Page 46
2.4 Experimental verification of additive equilibrium theory......Page 54
References......Page 74
3.1 Relative retention values in gas chromatography and chromatographic identification procedures......Page 81
3.2 Effect of the solid support on relative retention values......Page 85
3.3 Relative retention values in gas-liquid-solid chromatography and invariant relative retention values (theory and experimental determination)......Page 90
References......Page 107
4.1 Effect of sorbent particle diameter......Page 112
4.2 Role of a solid support porous structure......Page 120
4.3 Effect of the adsorptional properties of a solid support......Page 131
References......Page 134
5.1 Effect of the phase ratio (stationary liquid phase to solid adsorbent) on the characteristics of chromatographic resolution......Page 138
5.2.1 Sorbent: stationary liquid phase on a solid support......Page 143
5.2.2 Sorbent: stationary liquid phase on an active adsorbent......Page 147
5.3 Capillary columns......Page 155
References......Page 157
Chapter 6 Effect of Adsorption and Catalytic Activity of a Solid Support on the Quantitative Analysis of Data......Page 161
6.1 Irreversible or quasi-irreversible adsorption of chromatographed compounds on the solid support and its effect on the results of quantitative analysis......Page 165
6.2 Chemical transformation at the solid support surface......Page 188
References......Page 194
Chapter 7 Determination of Equilibrium Parameters of Absorption Interaction Between Chromatographed Substances and Stationary Liquid Phase......Page 199
References......Page 210
Chapter 8 Determination of Physicochemical Parameters for Adsorption of Chromatographed Compounds at the Gas-Stationary Liquid Phase and Stationary Liquid Phase-Solid Support Interfaces......Page 212
References......Page 223
Chapter 9 Effect of Solid Support on the Conditioning and Aging of Chromatographic Columns......Page 225
References......Page 242
Conclusion......Page 245
Index......Page 246