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Gas diffusion in branched and crosslinked polymers: A model of treelike clusters

✍ Scribed by R. M. Khalikov; G. V. Kozlov; G. E. Zaikov


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
58 KB
Volume
99
Category
Article
ISSN
0021-8995

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The development of a new model for the diffusion of gas molecules in glassy polymers is presented which utilizes concepts from free volume theory and relies on a dual-mode interpretation of sorptive dilation in glassy polymers. Three assumptions are made in the development of the model. First, the f