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Gas chromatography of homologous esters : VII. The retention behaviour of pyruvate esters and related carbonyl and carboxyl compounds

✍ Scribed by J.K. Haken; D.K.M. Ho; Carolyn E. Vaughan


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
549 KB
Volume
106
Category
Article
ISSN
1873-3778

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## Abstract Variation of the values of free energy of sorption of the methylene unit has been studied in the homologous series of __n__‐alkyl methyl ketones, __n__‐alkyl butyl ketones, __n__‐alkyl acetates, and methyl esters of carboxylic acids, depending on the homologue number and the temperature

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Using gas-liquid chromatography with silicone grease, Apiezon M and polydiethylene glycol succinate as the stationary phases, the retention volumes of methyl esters of fatty acids have been determined at zoo0 and at 220~. The acids studied included s-odd and even-numbered saturated acids from C, to