Gas chromatography of homologous esters : VII. The retention behaviour of pyruvate esters and related carbonyl and carboxyl compounds
β Scribed by J.K. Haken; D.K.M. Ho; Carolyn E. Vaughan
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 549 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1873-3778
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π SIMILAR VOLUMES
The division of the retention indices of simple carbonyl-containing compounds into components indicative of apolar and polar interactions is reported. About 200 compounds in 40 homologous series were studied, including simple esters with branching and unsaturation in both the alkyl or alcohol and ac
## Abstract Variation of the values of free energy of sorption of the methylene unit has been studied in the homologous series of __n__βalkyl methyl ketones, __n__βalkyl butyl ketones, __n__βalkyl acetates, and methyl esters of carboxylic acids, depending on the homologue number and the temperature
Using gas-liquid chromatography with silicone grease, Apiezon M and polydiethylene glycol succinate as the stationary phases, the retention volumes of methyl esters of fatty acids have been determined at zoo0 and at 220~. The acids studied included s-odd and even-numbered saturated acids from C, to