Gas chromatography of esters : XII. Linear extrathermodynamic relationships
β Scribed by J.K. Haken; Ann Nguyen; M.S. Wainwright
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 1010 KB
- Volume
- 178
- Category
- Article
- ISSN
- 1873-3778
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β¦ Synopsis
A series of five simple and inter-related extrathermodynamic relationships developed by Fellous and co-workers with several series of ethers and suggested to be applicable to homologous series of any functional class have been examined with an extensive series of alkyl esters. The low-polarity esters with alkyl substituents which are not equivalent as are those of the ethers, present a more realistic series to determine general application.
π SIMILAR VOLUMES
The retentiqn behaviour of several series of unsaturated homologous esters or; a non-polar stationary phase is reported together with correlations that are possibly due to the structure of the compounds, and the influence of the boiling point is considered.
The retention behaviour of a number of series of l~on~ologous esters on a nonpolar stationary phase is reported together with correlations that are possible due to the structure of the compounds. The influence of the boiling point on retention is shown and the anomalous behaviour of methyl and isopr