Gas chromatographic column for the storage of sample profiles

✍ Scribed by Jean-Marie D. Dimandja; José R. Valentín; John B. Phillips

• Publisher: Elsevier Science
• Year: 1994
• Tongue: English
• Weight: 758 KB
• Volume: 299
• Category: Article
• ISSN: 0003-2670
• DOI: 10.1016/0003-2670(94)00306-8

✦ Synopsis

The concept of a sample retention column that preserves the true time profile of an analyte of interest is studied. This storage system allows for the detection to be done at convenient times, as opposed to the nearly continuous monitoring that is required by other systems to preserve a sample time profile. The sample storage column is essentially a gas chromatography column, although its use is not the separation of sample components. The functions of the storage column are the selective isolation of the component of interest from the rest of the components present in the sample and the storage of this component as a function of time. Using octane as a test substance, the sample storage system was optimized with respect to such parameters as storage and readout temperature, flow rate through the storage column, column efficiency and storage time. A 3-h sample profile was collected and stored at 30 degrees C for 20 h. The profile was then retrieved, essentially intact, in 5 min at 130 degrees C.