Gas chromatographic analysis of Chlorinated Biphenyls
โ Scribed by Harold Weingarten; William D. Ross; James M. Schlater; Guthrie Wheeler Jr.
- Publisher
- Elsevier Science
- Year
- 1962
- Tongue
- English
- Weight
- 282 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0003-2670
No coin nor oath required. For personal study only.
โฆ Synopsis
In the course of research it became necessary to cstrzblish a rapid and rclinblc analytical method for biphcnyl, and the mono-and clichlorobiphenyls.
Although infra-red methods were nclcquatc for two or three component misturesl WC frequently had to deal with mistures containing from 4 to IO components. Gas chromatogrnphy provided not only i1 qualitati\*c but also il qunntitative method.
A Barber-Colman Model 20 gils chromntograph equippccl with ;1 strontium-c)o diode argon ionization detector WLS used. Capillnry colii~rwts The zoo-ft. stainless steel polypropylcnc glycol 750 (Dow Chemical Co.) column (PIG No. I) was originally purchasccl from Rarhcr-Colman. Howcvor, through cs-'I'h 131.
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The 13C NMR spectra of 48 chlorinated biphenyls are presented. The I3C shifts of the individual carbons are interpreted by the additive contributions from the substituent effect of a chlorine atom, and by the repulsive interaction of chlorine atoms substituted in a crowded relationship on the biphen
Japan preted by additive contributions from the substituent effects of chlorine atoms. YANAGrSAWA' KIKUKo Complete analyses of the 400 MHz 'H NMR be addressed) and OSAMU were carried out in order to obtain the 'H chemical shifts and couolina constants. The HAYAMIZU (to whom ComesPondence spectra of